纤维混凝土在冻融循环、冻融--氯盐共同作用下的耐久性试验研究

本文设计了混凝土在冻融循环单独作用或与氯化钠溶液复合作用下的耐久性试验方法，通过大量系统试验表明在混凝土的拌合料中掺进一定数量的聚丙烯纤维，可以有效地防止混凝土早期出现的龟裂，降低混凝土的渗透性，从而显著提高其耐久性，总结了聚丙烯纤维混凝土在双重破坏因素作用下的损伤规律及损伤复合效应，同时通过试验与理论分析，总结了聚丙烯纤维、钢纤维和膨胀剂对混凝土损伤抑制的复合效应。     

聚丙烯纤维混凝土路面耐久性的试验研究

为了验证掺入聚丙烯纤维的方法提高混凝土路面耐久性指标的可行性,进行了聚丙烯纤维混凝土路面耐久性的室内试验研究,探讨了不同纤维体积掺量对混凝土路面抗冻性和抗裂性的影响。实验表明,聚丙烯纤维的加入显著改善了混凝土路面的抗冻性能,表现为聚丙烯纤维混凝土路面受冻后抗折强度和抗压强度的损失明显降低,而聚丙烯纤维的加入对混凝土路面干燥收缩的影响不大,聚丙烯纤维可以有效改善混凝土路用耐久性指标。     

聚丙烯改性技术及制品应用

介绍了我国聚丙烯质轻、耐腐蚀、易加工、力学均衡性好、价廉,但低温脆性大和成型收缩率大的特点、世界用量等发展现状及改性技术,列举一些改性技术实例,说明在复合材料中聚丙烯既可以作为增强材料也可以作为基体等情况。     

基于静态压缩试验的缓冲包装材料性能对比分析

聚苯乙烯和聚丙烯缓冲包装材料都是粘弹性材料.通过对这2种材料在不同约束(不同加压速度,不同压缩次数)条件下进行静态压缩试验,研究这2种材料的静态特性.试验得到的数据运用Matlab软件,采用最小二乘法进行曲线拟合,得出材料的应力-应变曲线和缓冲系数-最大静应力曲线.最后分析这2种材料的静态压缩特性,并比较它们的异同点.     

竹纤维碱化改性对竹纤维/聚丙烯复合材料性能的影响

用不同浓度的NaOH 溶液对竹纤维(bamboo fiber, BF) 进行表面改性处理, 一定温度烘干后, 通过熔融挤出 制备了竹纤维/聚丙烯(BF/PP) 竹塑复合材料。采用示差同步扫描热分析仪(TG-DSC)、红外光谱(FTIR)、X 射线衍 射仪(XRD) 和扫描电镜(SEM) 等对预处理前后BF 的结构进行表征, 并研究了复合材料的力学性能。结果表明: 改 性后BF 的热稳定性升高, 形成疏松的纤维束; 复合材料的力学性能显著提高。其中用3% 的NaOH 溶液改性BF 制 备的复合材料的力学性能最佳, 冲击强度较纯PP 可提高100%, 屈服强度提高14.8%。复合材料冲击断面SEM 显 示, 一定浓度的NaOH 溶液改性可以明显提高BF 与PP 基体树脂间的相容性。     

基于ANSYS的再生混凝土梁抗裂性能有限元分析

为分析不同掺量硅粉和聚丙烯纤维对再生混凝土梁抗裂性能的影响,对5根再生混凝土梁的开裂荷载、极限荷载、应力分布和荷载-挠度曲线进行了ANSYS有限元分析。结果表明：硅粉和聚丙烯纤维的掺入,提高了再生混凝土的强度和整体刚度,使得梁抵抗拉应力的能力提高,抗裂性能增强、延性提高,开裂荷载和极限荷载均增大。当硅粉掺量为8%,聚丙烯纤维掺量为0.9 kg/m3时,试件的开裂荷载和极限荷载达到最大值,分别为23.66 kN和128.5kN,较SF₀P₀均提高20%以上。     

Nucleation and growth behavior of β-nucleated iPP during shear induced crystallization investigated by in-situ synchrotron WAXS and SAXS

Polymer crystallization under flow was investigated because final properties of polymers strongly depend on the crystalline structure and morphology formed during processing. In-situ synchrotron WAXS and SAXS were used to investigate the structure formation and morphological developments during quiescent and shear-induced crystallization of iPP with 3 different concentrations (0.01, 0.03 and 0.1 wt%) of β-nucleating agent. Under quiescent conditions, a high β-content was obtained at all those concentrations indicating the high β-nucleating efficiency of the nucleating agent. After application of shear, the β-nucleating ability at small concentration was retained, while at larger concentrations it was strongly retarded. Furthermore, the addition of β-nucleating agent was beneficial for the molecular alignment during processing, the anisotropic particles of β-nucleating agent were much more effective to align the molecular chains in the flow direction compared to isotropic ones. A crystallization scheme for the iPP β-nucleating agent under shear was proposed.     

Atom transfer radical polymerization (ATRP): A versatile and forceful tool for functional membranes

The progress in atom transfer radical polymerization (ATRP) provides an effective means for the design and preparation of functional membranes. Polymeric membranes with different macromolecular architectures applied in fuel cells, including block and graft copolymers are conveniently prepared via ATRP. Moreover, ATRP has also been widely used to introduce functionality onto the membrane surface to enhance its use in specific applications, such as antifouling, stimuli-responsive, adsorption function and pervaporation. In this review, the recent design and synthesis of advanced functional membranes via the ATRP technique are discussed in detail and their especial advantages are highlighted by selected examples extract the principles for preparation or modification of membranes using the ATRP methodology.     

A facile one‐step method for spherical support preparation of Ziegler‐Natta catalyst

This study reports a novel one‐step method to synthesize a new spherical support for Ziegler‐Natta catalyst under moderate condition. The support is obtained from a dispersion system where the particle stabilizer polyvinylpyrrolidone plays a main role to stabilize the spherical particles. The new chemical of the support is CH₃CH₂OMgOCH(CH₂Cl)₂, which is first reported here, has been approved by newly filed patents and also confirmed by solution NMR, solid state NMR, pyrolysis‐gas chromatography‐mass spectrometry (Py‐GC‐MS), and ICP‐MS. The support and catalyst particles have uniform distributions. The catalyst prepared from this support has been evaluated with high activity. The polypropylene obtained has high isotacticity. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 41014.     

聚丙烯2500H助剂配方优化研究

通过优化设计聚丙烯2500H助剂配方中的抗氧剂和滑石粉添加量,考察了采用不同助剂配方对聚丙烯2500H的力学性能、抗热氧化性能和其他基本物理性能的影响。结果表明:优化后的助剂配方中,抗氧剂1010添加量为600μg/g,抗氧剂168添加量为600μg/g,滑石粉添加量300μg/g的助剂配方为最优配方。采用该配方在保证聚丙烯2500H基本物性的条件下,可以降低助剂添加量,节约产品生产成本。